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Article Thumbnail Image Coal fires occur in nature spontaneously, contribute to increases in greenhouse gases, and emit atmospheric toxicants. Increasing interest in quantifying coal fire emissions has resulted in the adaptation and development of specialized approaches and adoption of numerical modeling techniques...
Monday, June 17, 2013  Type: Outside Publication

Article Thumbnail Image Mercury is a toxic pollutant. In its elemental form, gaseous mercury has a long residence time in the atmosphere, up to a year, allowing it to be transported long distances from emission sources. Mercury can be emitted from natural sources such as...
Tuesday, November 13, 2012  Type: Publication

Article Thumbnail Image Electron beam microanalysis of coal samples in U.S. Geological Survey (USGS) labs confirms that As is the most abundant minor constituent in Fe disulfides in coal and that Se, Ni, and other minor constituents are present less commonly and at lower concentrations than those for As.
Tuesday, May 01, 2012  Type: Outside Publication

Article Thumbnail Image Dozens of natural and human-induced coal fires are active in the Powder River Basin (PRB) of southeast Montana and northeast Wyoming, the largest source of coal produced in the United States. Coal fires exhibit surface features similar to those found above high-temperature geothermal systems...
Tuesday, March 06, 2012  Type: Outside Publication

Article Thumbnail Image Coal fires occur in all coal-bearing regions of the world and number, conservatively, in the thousands. These fires emit a variety of compounds including greenhouse gases. However, the magnitude of the contribution of combustion gases from coal fires to the environment is highly uncertain...
Tuesday, October 25, 2011  Type: Outside Publication

Article Thumbnail Image Geochemistry is a constantly expanding science. More and more, scientists are employing geochemical tools to help answer questions about the Earth and earth system processes. Scientists may assume that the responsibility of examining and assessing the quality of the geochemical data they generate is...
Tuesday, September 13, 2011  Type: Publication

Article Thumbnail Image Increased demand for energy is driving rapid development of oil and gas, uranium, geothermal, wind, and solar sources of energy throughout the Western United States. Much of the energy development is occurring on public lands, which represents about 40 percent of Colorado and New Mexico...
Monday, June 20, 2011  Type: Publication

Article Thumbnail Image Constraints on drainage management in the western San Joaquin Valley and implications of proposed approaches to management were recently evaluated by the U.S. Geological Survey (USGS).
Monday, September 27, 2010  Type: Publication

Article Thumbnail Image This study presents >5 cumulative years of tropospheric mercury (Hg) speciation measurements, over the period of 2003–2009, for eight sites in the central and eastern United States and one site in coastal Puerto Rico.
Wednesday, September 22, 2010  Type: Outside Publication

Article Thumbnail Image Atmospheric emissions, transport and deposition of mercury (Hg) are key processes leading to the global mercury contamination problem (Wiener et al., 2003). Mercury emissions to the atmosphere arise from natural and anthropogenic sources, and by re-emission of previously deposited...
Monday, May 17, 2010  Type: Outside Publication
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Overview

Environmental Geochemistry assesses the impacts of energy resources on the environment using a primarily geochemical/geologic approach. Energy resources contain substances that, when mobilized into air, or natural waters (surface and ground water), deposited/adsorbed on soils or sediments, or incorporated into foodstuffs, pose a potential environmental and human health risk. The project examines environmental impacts of toxic substances mobilized from: (1) energy resources in the geologic environment, (2) the extraction, transport, storage, and utilization of energy resources, and (3) the disposal of energy waste products.

Bill Orem
Project Chief


Mercury (Hg) is an important trace element present in the environment because 1) mercury can occur in organic forms, such as methylmercury, which are highly toxic and can be bioconcentrated, biomagnified, and bioaccumulated in the food web, and 2) as an atmospheric constituent mercury can be transported long distances from its original source and eventually deposited back to the surface, possibly hundreds or thousands of miles away.

Mercury has a complex biogeochemical cycle which allows it to be transferred between different ecosystem reservoirs and exhibit chemical transformations that control its behavior and toxicity (Figure 1.). Researchers in the USGS Eastern Energy Resources Science Center and their colleagues are actively involved in studying the behavior and occurrence of mercury in the environment, as well as human exposures to mercury. Currently research is focused in five areas.

Simplified biogeochemical cycle of Mercury
Figure 1. Simplified biogeochemical cycle of
Mercury in the environment:
View larger image.
Blebs of exposed mercury
Photo: Blebs of elemental mercury exposed
in a breached conduit at the defunct
Nikitovka mercury plant, Gorlovka, Ukraine.

Allan Kolker
Project Chief

Mark Engle
Lead Scientist


Selenium is a naturally occurring element and an important micronutrient essential for all living organisms. Selenium is also used in many commercial applications including glass decolorizing, metallurgical additives, machining of ferrous and nonferrous alloys, pigments, copier photoreceptors, and in semiconductor and photocell industries.

Although selenium is essential, large concentrations can be toxic, particularly to aquatic wildlife. Human activities such as coal mining, industrial processing, agricultural runoff and leaching of natural soluble selenium can concentrate selenium in excess of the regulatory limits of 5 micrograms per liter (µg/L) and affect wetland habits. The USGS Energy Resources Program researches the geologic location, extent and distribution, and environmental affects on human health and the landscape and provides this information to decision-makers.

Frequently Asked Questions Pertaining to Selenium

Decision Analysis

Frank Dulong
Lead Scientist

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Research

Mercury Emissions from China
Mercury Emissions from China

Mercury Emissions from China

The Peoples' Republic of China produces and consumes the largest quantity of coal in the world; about 1.7 billion tons produced in 2003 (Figure 1). Current projections, rough estimates at best, forecast coal consumption to be 3.3 billion tons by 2020. Although the nationwide percentage of electrical production from coal is falling due to increased power generation efficiency, China will burn more coal than any other country for the... [+]

foreseeable future. China also is estimated to be the largest producer of mercury emissions (Dastoor and Larocque, 2004). A recent comprehensive study of anthropogenic mercury emissions in China (Streets et al., 2005) yielded a figure of 536 t of mercury for the year 1999 with coal combustion (all types) accounting for 38% of the total. Atmospheric mercury emission is an international problem as the troposphere provides effective global transport of mercury. Although the estimates vary, China produces about three times more mercury per ton of coal burnt than the USA because of the lack of modern pollution technology and limited use of cleaned coal. Knowledge of the mercury content, mode of occurrence, and regional distribution in Chinese coal is vital in order to assess the global atmospheric contribution from Chinese coal combustion.

Under the aegis of the USGS WoCQI Program, we have collected and analyzed 305 Chinese coal samples from mines with the highest production from 25 provinces, municipalities, or autonomous regions, which thus reflects much of the coal currently supplied for power generation and industrial use. The method of determination was routine cold-vapor atomic absorption spectroscopy using two methods of sample dissolution. The arithmetic mean, on an as-determined, whole-coal basis, of 305 samples is 0.15 ppm (1 sigma = 0.14), with a minimum of 0.02 ppm and a maximum of 0.69 ppm. All data averaged to a dry basis is 0.16 ppm. A small percentage (~ 9 %) of the mercury data were below the method detection limit of 0.02 ppm. Duplicate analyses and inter-laboratory comparisons suggest that analytical uncertainties can arise from imperfect sample splitting using a mesh sample size in some samples.

Research continues to assess relationships between mercury content in coal and other measured chemical and physical parameters and topical studies related to mercury mineralization in coals of Guizhou Province.

References

Dastoor, A.P., Larocque, Y., 2004, Global circulation of atmospheric mercury: a modeling study: Atmospheric Environment, v. 38, p. 147-161.

Streets, D.G., Hao, J., Wu, Y., Jiang, J., Chan, M., Tian, H., Feng, X., 2005, Anthropogenic mercury emissions in China, v. 40, p. 7789-7806.


Mercury in Coal
Mercury Deposition Network

Mercury in Coal

USGS research provides information on the amount and forms of mercury and other elements present in U.S. Coals (Tewalt et al., 2001). Understanding the distribution of mercury in coal is especially important in light of recent U.S. EPA rulings, outlining plans to limit mercury emissions from U.S. coal-fired utilities. Using selective chemical leaching (Figure 1), laser-ablation ICP-MS (Figure 2), and other approaches, USGS results... [+]

show that pyrite is the primary host of mercury in bituminous coals, whereas the proportion of mercury present in organic parts of coal is generally greater in low-rank (lignite and sub-bituminous) coal. Many Eastern U.S. bituminous coals are “cleaned” prior to use in utility power stations, to reduce sulfur emissions. This coal preparation reduces sulfur content, primarily by removing pyrite from coal. In doing so, a portion of the mercury present may also be removed, as a co-benefit to sulfur reduction. Currently about 35% of the mercury that goes into coal-fired utility power stations in the U.S. is captured by air pollution control devices, whose primary function is to trap particulates from coal combustion, or sulfur emitted from flue gasses. Under the EPA Clean Air Interstate Rule (CAIR), the initial phase of mercury reductions from coal-fired utility power station will primarily result as a co-benefit of reducing other pollutants with existing control technology. Under the second phase of the plan, the EPA Clean Air Mercury Rule (CAMR), greater reductions of mercury emissions are specified, probably requiring new mercury-specific control technology for utilities. By understanding the mode of occurrence of mercury in coal, and the concentration of constituents that affect capture of mercury, such as chlorine, the USGS provides information needed to help predict and control mercury emissions.

Selective leaching results graph for 15 coal samples
Figure 1. Selective leaching results for 15 coal samples (12 from the U.S.). Yellow bars indicate the proportion of mercury leached with nitric acid, thought to be contained in sulfide minerals, such as pyrite. The fraction of mercury not leached (100 percent minus total bar height) represents organic-associated mercury not removed by the leaching process. Arrows indicate minimum values. Figure is from Palmer and others, 1998.

Plot of mercury in pyrite plotted versus arsenic content
Figure 2. Plot of mercury in pyrite plotted versus arsenic content (log scale) based on reconnaissance laser ablation ICP-MS analysis of 6 U.S. eastern bituminous coal samples. Data points represent individual analysis points ranging in size from 10 to 50 micrometers. Results for pyrite grains analyzed indicate mercury concentrations that are 10’s to 100’s of times higher than mercury concentrations in the whole coal. Samples include an Ohio 5/6/7 blend (Ohio), Illinois #6 (Illinois), Pittsburgh Coal from West Virginia (Pitts), the Warrior Basin of Alabama (AL), the Upper Coalburg Coal from West Virginia (WV), and an eastern Kentucky coal (KY). Data are from Diehl and others, 2005 and Kolker and others, 2002.

References

Diehl, S.F., Goldhaber, M.B., Tuttle, M.L.W., Ruppert, L.F., Hatch, J.R., Koenig, A.E., and Lowers, H.A., 2005, Distribution of arsenic, selenium, and other trace elements in pyrite-filled structures in Appalachian coals of Alabama, Kentucky, and West Virginia: Proceedings of the 22nd International Pittsburgh Coal Conference, Pittsburgh, PA, September, 2005, 24 p., CD-ROM.

Kolker, Allan, Mroczkowski, S. J., Palmer, C. A., Dennen, K. O., Finkelman, R. B., and Bullock, Jr., J. H., 2002, Toxic substances from coal combustion- A comprehensive assessment, Phase II: Element modes of occurrence for the Ohio 5/6/7, Wyodak, and North Dakota coal samples: U.S. Geological Survey, Open File Report 02-224, 79 p.

Palmer, C. A., Mroczkowski, S. J., Finkelman, R. B., and Crowley, S. S., 1998, The use of sequential leaching to quantify the modes of occurrence of elements in coals: Proceedings of the Fifteenth Annual International Pittsburgh Coal Conference, 28 p., CD-ROM.


Mercury Deposition Network
Mercury Deposition Network

Mercury Deposition Network

The USGS in cooperation with researchers at the George Mason University Department of Chemistry, operate a mercury deposition precipitation sampler in Culpeper, Virginia. The site is part of the Mercury Deposition Network (MDN), a cooperative U.S. and Canadian network of mercury wet deposition samplers deployed to characterize mercury deposition via rain and snow (i.e., wet deposition). The sampler has been running... [+]

continuously since November of 2002 and was modified to collect samples for trace metal analysis beginning in November of 2004 (Figure 1).

View of the VA-08 MDN site
Figure 1. View of the VA-08 MDN site showing the recording rain gauge (foreground) and an MDN precipitation collector (background). Precipitation samples are collected through one of two chimneys on the left side of the collector (one for mercury and one for other trace metals) when the moisture sensor activates the lid covering the sample chimneys. Photo by Allan Kolker, USGS.

Data generated from the sampler include weekly mercury and trace element concentration and deposition. These data show variations in mercury and other trace metal wet deposition across the country (Figure 2). Statistical and air mass trajectory modeling are being used to identify potential sources for the mercury and other trace metals, and suggest processes important in controlling wet deposition. Data from the VA-08 site are also being compared to data from the nearby Shenandoah National Park-Big Meadows MDN site (VA-28). The sites are within 31 kilometers of one another but vary in elevation (VA-08 = 183 m; VA-28 = 1,074 m) allowing for investigation on the effect of elevation on deposition.

MDN results for 2004, including the Culpeper VA-08 site.
Figure 2. MDN results for 2004, including the Culpeper VA-08 site. Warmer colors indicate areas of higher wet deposition while cooler colors represent lower yearly deposition. Mercury deposition and concentration maps available from the National Atmopsheric Deposition Program – Mercury Deposition Network.


Atmospheric Mercury Speciation
Atmospheric Mercury Speciation

Atmospheric Mercury Speciation

The behavior of mercury in the atmosphere depends upon its form, or species. Elemental mercury (Hgo) is typically not very reactive with a global lifetime of a few months to a year and is thought to be transported significantly in the troposphere. Reactive gaseous mercury (RGM) species, are not well characterized chemically but are thought to be gaseous Hg(II)-bearing molecules such as HgCl2(g). RGM species are... [+]

notable for being quickly deposited from the atmosphere to the surface and are thought to be readily available for conversion to methyl mercury, a highly toxic form of mercury. Particulate mercury (Hg-P) is also quickly deposited and is often found in high concentrations near combustion sources. Although much lower in proportion than Hgo, the greater reactivity and deposition rates of RGM and Hg-P make them a greater environmental concern. Chemical reactions that occur in the atmosphere can transform mercury between these various species.

USGS Mobile Mercury Laboratory operated by the USGS Wisconsin Water Science Center.
Figure 1. USGS Mobile Mercury Laboratory operated by the USGS Wisconsin Water Science Center. Instruments include an atmospheric mercury speciation unit; NOx, SOx, O3, and PM2.5 analyzers; a meteorological station; and a wet deposition sampler. Photo by James Robinson, USGS.

Recently, USGS researchers from the Energy Resources Program and the Water Mission Area have started characterizing tropospheric Hgo, RGM, and Hg-P concentrations in southern Alabama, near the Gulf of Mexico. The project relies upon the USGS Mobile mercury laboratory (Figure 1) which measures near real-time concentrations of the three mercury species (Figure 2). Potential sources of mercury to the region include a nearby coal-fired power plant and industrial emissions from nearby cities such as Mobile, Alabama; Pensacola, Florida; and New Orleans, Louisiana. Natural processes are also being investigated that could cause conversion of Hgo to RGM or Hg-P.

Plot of preliminary RGM, Hg-P, and Hgo concentration data
Figure 2. Plot of preliminary RGM, Hg-P, and Hgo concentration data determined by the atmospheric mercury speciation unit on the USGS Mobile Mercury Laboratory deployed at Weeks Bay, Alabama from 6/6/05 to 6/16/05 (Julian days 157 to 167). The gap in the data is a result a shut down during tropical storm Arlene.

Additional total suspended particulate samplers were used to collect atmospheric particulates on filters that are analyzed for mercury as well as a variety of other constituents (Figure 3). Combining the mercury speciation data with multivariate statistical methods and air mass trajectory modeling, potential sources of mercury and other trace metals can potentially be identified as well as processes that produce RGM and Hg-P.

Gulf Shores State Park, Alabama particulate samplers
Figure 3. High-volume (left) and low-volume (right) total suspended particulate samplers deployed at Gulf Shores State Park, Alabama. The high volume sampler collects particles on a large filter located under the triangular lid. The high volume filters were analyzed for mercury and soluble components including Cl and SO4. The low volume sampler contains two filters housed in filters packs at each end of the tripod crossbar. One filter is analyzed for mercury and the other for other trace metals. Photo by Allan Kolker, USGS.


Mercury Exposure in Ukraine
Mercury Exposure in Ukraine

Mercury Exposure in Ukraine

High levels of mercury are present in Gorlovka, Ukraine (pop. 320,000), due to mining and processing of mercury that ceased in 1991, leaving a series of abandoned open pits, a now closed mercury extraction plant (Figure 1), extensive mine tailings, and several tailings ponds. Past use of extreme mercury-enriched coal (Figure 2), produced as a byproduct of mercury mining, and current industrial use of local coal from nearby mines, pose... [+]

potential hazards to Gorlovka. An integrated environmental/human health study is underway to define mercury exposure levels, assess possible health effects to exposed individuals, and determine the feasibility of further epidemiologic studies on a larger scale. The study, Feasibility of Assessing Health Risks from Long-term Mercury Exposure in Gorlovka, Ukraine funded by the U.S. Civilian Research and Development Foundation, is part of USGS studies on health effects of inorganic substances in coal.

Defunct mercury processing plant at Nikitovka Mines, Gorlovka, Ukraine
Figure 1. Defunct mercury processing plant at Nikitovka Mines, Gorlovka, Ukraine, operated from 1968 to 1991. A small portion of this site is currently used to recycle fluorescent lamps and batteries to recover mercury. Photo by Allan Kolker, USGS.

Graph showing average mercury content of four Nikitovka coal samples
Figure 2. Average mercury content of four Nikitovka coal samples collected by USGS scientists and collaborators at Donetsk National Technical University, compared to mercury in active mines of the region and U.S. averages for in-ground coal, and for the Warrior Basin of northern Alabama. U.S. coal data are from Bragg et al., 1998. Note break in vertical scale between 1 and 10 ppm mercury.

Current work on human mercury exposure in Gorlovka began in August, 2005, following a more general study of mercury-rich coals in the region, funded by the NATO Science Program (Figure 2). In the current study, a group of 30 workers at a mercury recycling facility on the site of the defunct mercury extraction plant was selected for sampling hair, nails, blood, and urine, to assess their mercury exposure. In conjunction with tissue sampling, environmental samples were taken to assess mercury levels and potential exposure near the mercury mines and over a larger portion of Gorlovka (Figure 3). Additional tissue sampling is planned for non-exposed individuals in Gorlovka and in a nearby control municipality. Our work in Ukraine has the potential to be an important case study of human exposure to mercury.

Environmental sampling in Gorlovka by Kathryn Conko (USGS)
Figure 3. Environmental sampling in Gorlovka by Kathryn Conko (USGS) to assess exposure of residents to mercury. Photo by Allan Kolker, USGS.


Source Characterization and Identification of Natural and Anthropogenic Harmful Materials
Source Characterization
and Identification

Source Characterization and Identification of Natural and Anthropogenic Harmful Materials

Energy resources like coal, oil and natural gas are the pillars of our modern industrial society and they are the major catalyst for the fast paced technological advancement. However, their exploitation has side effects whose magnitude has triggered widespread concerns in the recent years, as the public has become more aware of the concept of global warming or... [+]

the increasing incidence of diseases like cancer or asthma. At the forefront of geomedical research, the USGS has the role to provide the public and the policymakers with the scientific information needed to account for the environmental and human health consequences of energy resource extraction, processing, transportation and use. The USGS is addressing these issues in an interdisciplinary context, through a dedicated project entitled “Impacts of Energy Resources on Human Health and Environmental Quality”. Several research topics include: Balkan Endemic Nephropathy (BEN), “panendemic nephropathy” (i.e., diseases similar to BEN but outside the Balkans), environmental contamination related to mountain top mining (MTM) and coal slurry in the Appalachian Basin and the release of toxic substances in energy combustion products.

Mountain top mining (MTM) in the Appalachian Basin
Figure 1. Mountain top mining (MTM) in the
Appalachian Basin has adverse consequences
on the environment and human and
ecosystems health. USGS in collaboration with
West Virginia University in Morgantown is
addressing issues as water, air and soil
pollution caused by MTM. Enlarge Image


 
Coal, in native or processed form, is a major source of organic pollutants
Figure 2. Coal, in native or processed form, is
a major source of organic pollutants that can
leach into groundwater or streams and affects
humans or aquatic organisms. This photo
shows a seam of Pliocene lignite from
Romania; such low rank coal deposits are
widespread in the Balkan endemic nephropathy
(BEN) areas and are supposed to contain
nephrotoxic and carcinogenic organic
substances that contaminate drinking
groundwater and are causing the fatal kidney
disease and urinary tract cancers.
Enlarge Image

References:

Orem W., Tatu C., Pavlovic N., Bunnell J., Kolker A., Engle M. and Ben Stout (2009) Health Effects of Energy Resources. U.S. Geological Survey Fact Sheet 2009-3096.

Kolker A., Engle, M., Stracher G., Hower J., Prakash A., Radke L., ter Schure A., Heffern E (2009) Emissions from coal fires and their impact on the environment: U.S. Geological Survey Fact Sheet 2009-3084.

Orem W.H., Bunnell J.E. Tatu C.A., Pavlovic N., and (2009) Toxicological pathways of relevance to medical geology. In: Encyclopedia of Environmemntal Health (Nriagu J., editor), Elsevier Science 2011.

Contact: William H. Orem borem@usgs.gov


Movement and Alteration of Disease-causing Agents
Movement and Alteration of
Disease-causing Agents

Movement and Alteration Predictions of Chemical, Infectious, and other Disease-causing Agents over Time and Space

Air can be a significant source of all sorts of human health hazards and compared to water and soil, transport of noxious chemicals and particulates or pathogenic microorganisms occurs much faster and can affect populational groups on a larger scale. USGS has been involved in several projects exploring the... [+]

links between human health and air quality alterations due to fossil fuel extraction/mining and combustion.

The presence in air of fine particulate matter 2.5 micrometers in size, called PM2.5, and originating from coal combustion and other sources, is a serious health concern. This material is small enough to be readily lodged in small interstices (alveoli) in the lungs. The U.S. Environmental Protection Agency (USEPA) air-quality regulatory standards are based on limits in the amount of PM2.5, while the USGS can provide more detailed knowledge on the chemistry, mineralogy, surface characteristics and potential toxicity of such particles.

A multi-agency study in the Navajo Nation of New Mexico has focused on the extent of human exposure to contaminants in particulate matter derived from domestic coal combustion and links to respiratory disease. The study was based on both epidemiological data examining the incidence of respiratory diseases as well as on field studies measuring indoor and outdoor air quality, including PM2.5. Air sampling in the Navajo Nation has shown that in winter, when coal stoves are in use, some homes exceed the USEPA 24-hour ambient (outdoor) PM2.5 standard. Analysis of PM2.5 samples from Navajo homes burning coal shows an abundance of organic compounds indicative of a coal source.

References:

Orem W., Tatu C., Pavlovic N., Bunnell J., Kolker A., Engle M. and Ben Stout (2009) Health Effects of Energy Resources. U.S. Geological Survey Fact Sheet 2009-3096.

Kolker A., Engle, M., Stracher G., Hower J., Prakash A., Radke L., ter Schure A., Heffern E (2009) Emissions from coal fires and their impact on the environment: U.S. Geological Survey Fact Sheet 2009-3084.

Bunnell J. E., Garcia L.V, Furst J.M., Lerch H., Olea R.A., Suitt S.E., and Kolker A. (2010) Navajo coal combustion and respiratory health near shiprock, new Mexico. J Environ Public Health. 2010:260525.

Contact: William H. Orem borem@usgs.gov

Multimedia

USGS CoreCast:

Mercury Contamination in Fish
USGS Podcast (Episode 102)

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Coal and Human Health
USGS Podcast (Episode 103)

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