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Thursday, April 12, 2018

Experimental investigation of the role of rock fabric in gas generation and expulsion during thermal maturation: Anhydrous closed-system pyrolysis of a bitumen-rich Eagle Ford Shale

Outside Publication: Organic Geochemistry
Gold-tube pyrolysis experiments were conducted on miniature core plugs and powdered rock from a bitumen-rich sample of Eagle Ford Shale to investigate the role of rock fabric in gas generation and expulsion during thermal maturation. The samples were isothermally heated at...

Thursday, April 12, 2018

Evolution of sulfur speciation in bitumen through hydrous pyrolysis induced thermal maturation of Jordanian Ghareb Formation oil shale

Outside Publication: Fuel
Previous studies on the distribution of bulk sulfur species in bitumen before and after artificial thermal maturation using various pyrolysis methods have indicated that the quantities of reactive (sulfide, sulfoxide) and thermally stable (thiophene) sulfur moieties change following consistent trends under increasing thermal stress...

Thursday, March 15, 2018

The isometric log-ratio (ilr)-ion plot: A proposed alternative to the Piper diagram

Outside Publication: Journal of Geochemical Exploration
The Piper diagram has been a staple for the analysis of water chemistry data since its introduction in 1944. It was conceived to be a method for water classification, determination of potential water mixing between end-members, and to aid in the identification of chemical reactions controlling a sample set...

Wednesday, February 28, 2018

Distribution of rare earth elements in coal combustion fly ash, determined by SHRIMP-RG ion microprobe

Outside Publication: International Journal of Coal Geology
During coal combustion for electric power generation, rare earth elements (REE) are strongly retained in the ash fraction leading to significant enrichment compared to the REE content of the respective feed coals. Knowing how the REE are distributed in coal ash...

Thursday, January 04, 2018

Transgressive-regressive cycles in the metalliferous, oil shale-bearing Heath Formation (Upper Mississippian), central Montana

Outside Publication: Stratigraphy
The Upper Mississippian Heath Formation, which accumulated in the Big Snowy Trough of central Montana, has been known for three decades to contain mudrocks highly enriched in Zn, V, Mo, Ni and other metals, and source rocks for oil. The unit has more recently been...

Thursday, January 04, 2018

Nanoscale geochemical and geomechanical characterization of organic matter in shale

Outside Publication: Nature Communications
Solid organic matter (OM) plays an essential role in the generation, migration, storage, and production of hydrocarbons from economically important shale rock formations. Electron microscopy images have documented spatial heterogeneity in the porosity of OM at nanoscale...

Monday, December 18, 2017

Equilibrium and non-equilibrium controls on the abundances of clumped isotopologues of methane during thermogenic formation in laboratory experiments:

Implications for the chemistry of pyrolysis and the origins of natural gases

Outside Publication: Geochimica et Cosmochimica Acta
Multiply isotopically substituted molecules (‘clumped’ isotopologues) can be used as geothermometers because their proportions at isotopic equilibrium relative to a random distribution of isotopes amongst all isotopologues are functions of temperature. This has allowed measurements of...

Thursday, December 14, 2017

Significance of Northeast-Trending Features in Canada Basin, Arctic Ocean

Outside Publication: Geochemistry, Geophysics, Geosystems Journal

Synthesis of seismic velocity, potential field, and geological data from Canada Basin and its surrounding continental margins suggests that a northeast-trending structural fabric has influenced the origin, evolution, and current tectonics of the basin. This structural fabric has...

Friday, December 01, 2017

The hyper-enrichment of V and Zn in black shales of the Late Devonian-Early Mississippian Bakken Formation (USA)

Outside Publication: Chemical Geology
Black shales of the Late Devonian to Early Mississippian Bakken Formation are characterized by high concentrations of organic carbon and the hyper-enrichment (> 500 to 1000s of mg/kg) of V and Zn...





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